Archaeological use of non-destructive pXRF has been most systematically applied to the classification and provenancing of volcanic glass (obsidian) artefacts. Comparable work has yet to be developed for non-vitreous artefacts. We report results of pXRF analysis for a sample of grey to black (mafic) aboriginal hatchets from Sydney and adjacent coastal regions to the north and south. The study shows both broad and detailed classification is achievable depending on rock type and degree of elemental depletion or enrichment of the samples. PXRF analysis reveals not only distinct patterns of resource use between the three regions of this study but also enables a high degree of geographic resolution in the case of the basalt artefacts of our sample. We conclude that non-destructive pXRF is effective for reliable characterisation of non-vitreous stone artefacts that have a sufficiently complex and enriched compositional signature (i.e., unaltered basalts); with ~50% of the basalt hatchets in our sample matched with spatially and geologically specific sources.

Ground-edged artifacts were an important part of the Australian Aboriginal toolkit. They had practical day-to-day uses, but some had symbolic and social values that led to their movement across great distances. Australian provenance studies document long-distance Aboriginal exchange systems extending over hundreds of kilometers. The size and complexity of exchange systems and social networks were contingent upon resources and the productivity of a region's environment. Along the fertile, well-watered lands east of the Great Dividing Range, movement of objects may have been geographically more circumscribed than in drier areas to the west. One hundred and twenty-one mafic, ground-edged artifacts from the New South Wales (NSW) Central Coast and 368 geological specimens from potential sources were non-destructively analyzed by portable X-Ray fluorescence spectrometry. Results indicate the existence of a well-used basalt source within the region at Peats Ridge-Popran Creek as well as multiple local and non-local sources up to 430 km from Mangrove Mountain on the NSW Central Coast.