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Title
Advancements in Carbazole-Based Sensitizers and Hole-Transport Materials for Enhanced Photovoltaic Performance
Author(s)
Ibrayeva, Ayagoz
Abibulla, Urker
Imanbekova, Zulfiya
Baptayev, Bakhytzhan
Balanay, Mannix P
Publication Date
2024-11-01
Open Access
Yes
Abstract
<p>Carbazole-based molecules play a significant role in dye-sensitized solar cells (DSSCs) due to their advantageous properties. Carbazole derivatives are known for their thermal stability, high hole-transport capability, electron-rich (p-type) characteristics, elevated photoconductivity, excellent chemical stability, and commercial availability. This review focuses on DSSCs, including their structures, working principles, device characterization, and the photovoltaic performance of carbazole-based derivatives. Specifically, it covers compounds such as 2,7-carbazole and indolo[3,2-b]carbazole, which are combined with various acceptors like benzothiadiazole, thiazolothiazole, diketopyrrolopyrrole, and quinoxaline, as reported over the past decade. The review will also outline the relationship between molecular structure and power-conversion efficiencies. Its goal is to summarize recent research and advancements in carbazole-based dyes featuring a D-π-A architecture for DSSCs. Additionally, this review addresses the evolution of carbazole-based hole-transport materials (HTMs), which present a promising alternative to the costly spiro-OMeTAD. We explore the development of novel HTMs that leverage the unique properties of carbazole derivatives to enhance charge transport, stability, and overall device performance. By examining recent innovations and emerging trends in carbazole-based HTMs, we provide insights into their potential to reduce costs and improve the efficiency of DSSCs.</p>
Publication Type
Journal Article
Source of Publication
Molecules, 29(21), p. 1-28
Publisher
MDPI AG
Place of Publication
Switzerland
ISSN
1420-3049
File(s) openpublished/AdvancementsO'Reilly2024JournalArticle.pdf (8.24 MB)
Published Version
Fields of Research (FoR) 2020
Peer Reviewed
Yes
HERDC Category Description
Peer Reviewed
Yes
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